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| H | Libertad | - | Universidad de Chile | 1:1 (1:0) | ||
| R | Universidad de Chile | - | Libertad | 5:3 (1:1, 1:1, 1:1) i.E. | ||
| H: 17.05.2012 00:30 | R: 25.05.2012 03:30 | Sieger: Universidad de Chile | ||||
| H | Vasco da Gama - RJ | - | Corinthians SP | 0:0 (0:0) | ||
| R | Corinthians SP | - | Vasco da Gama - RJ | 1:0 (0:0) | ||
| H: 17.05.2012 02:50 | R: 24.05.2012 03:00 | Sieger: Corinthians SP | ||||
| H | Boca Juniors | - | Fluminense RJ | 1:0 (0:0) | ||
| R | Fluminense RJ | - | Boca Juniors | 1:1 (1:0) | ||
| H: 18.05.2012 00:45 | R: 24.05.2012 00:30 | Sieger: Boca Juniors | ||||
| H | Vélez Sarsfield | - | Santos FC | 1:0 (1:0) | ||
| R | Santos FC | - | Vélez Sarsfield | 4:2 (0:0, 1:0, 1:0) i.E. | ||
| H: 18.05.2012 03:00 | R: 25.05.2012 01:00 | Sieger: Santos FC | ||||
