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| H | Liverpool | - | Universidad Catolica | 2:1 (0:1) | ||
| R | Universidad Catolica | - | Liverpool | 3:0 (2:0) | ||
| H: 24.02.2021 01:30 | R: 03.03.2021 01:30 | Sieger: Universidad Catolica | ||||
| H | Universidad Cesar Vallejo | - | Caracas FC | 0:0 (0:0) | ||
| R | Caracas FC | - | Universidad Cesar Vallejo | 2:0 (1:0) | ||
| H: 24.02.2021 23:15 | R: 03.03.2021 23:15 | Sieger: Caracas FC | ||||
| H | Royal Pari | - | Guaraní | 1:4 (0:3) | ||
| R | Guaraní | - | Royal Pari | 1:1 (0:0) | ||
| H: 25.02.2021 01:30 | R: 04.03.2021 01:30 | Sieger: Guaraní | ||||
