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| H | Martos CD | - | Real Valladolid | 1:1 | ||
| R | Real Valladolid | - | Martos CD | 6:1 | ||
| H: 24.11.1981 | R: 08.12.1981 | Sieger: Real Valladolid | ||||
| H | Rayo Vallecano | - | Real Oviedo | 2:0 | ||
| R | Real Oviedo | - | Rayo Vallecano | 0:0 | ||
| H: 24.11.1981 | R: 08.12.1981 | Sieger: Rayo Vallecano | ||||
| H | Athletic Bilbao | - | Barcelona Atlètic | 2:0 | ||
| R | Barcelona Atlètic | - | Athletic Bilbao | 0:1 | ||
| H: 25.11.1981 | R: 09.12.1981 | Sieger: Athletic Bilbao | ||||
| H | Atlético Madrileño | - | Castilla CF | 1:0 | ||
| R | Castilla CF | - | Atlético Madrileño | 1:2 | ||
| H: 25.11.1981 | R: 10.12.1981 | Sieger: Atlético Madrileño | ||||
| H | FC Barcelona C | - | Atlético Madrid | 1:1 | ||
| R | Atlético Madrid | - | FC Barcelona C | 3:2 | ||
| H: 25.11.1981 | R: 08.12.1981 | Sieger: Atlético Madrid | ||||
| H | RC Celta | - | CD Alavés | 1:0 | ||
| R | CD Alavés | - | RC Celta | 5:4 i.E. | ||
| H: 25.11.1981 | R: 08.12.1981 | Sieger: CD Alavés | ||||
| H | Deportivo La Coruña | - | CD Tenerife | 2:1 | ||
| R | CD Tenerife | - | Deportivo La Coruña | 3:4 i.E. | ||
| H: 25.11.1981 | R: 09.12.1981 | Sieger: Deportivo La Coruña | ||||
| H | Elche CF | - | Gran Peña FC | 2:0 | ||
| R | Gran Peña FC | - | Elche CF | 1:2 | ||
| H: 25.11.1981 | R: 09.12.1981 | Sieger: Elche CF | ||||
| H | UD Las Palmas | - | Levante UD | 6:1 | ||
| R | Levante UD | - | UD Las Palmas | 0:0 | ||
| H: 25.11.1981 | R: 08.12.1981 | Sieger: UD Las Palmas | ||||
| H | CD Málaga | - | AD Ceuta | 3:2 | ||
| R | AD Ceuta | - | CD Málaga | n.gesp. | ||
| H: 25.11.1981 | R: 08.12.1981 | Sieger: CD Málaga | ||||
| H | CD Binéfar | - | RCD Mallorca | 3:1 | ||
| R | RCD Mallorca | - | CD Binéfar | 3:2 i.E. | ||
| H: 25.11.1981 | R: 09.12.1981 | Sieger: RCD Mallorca | ||||
| H | Real Murcia | - | UD Salamanca | 1:0 | ||
| R | UD Salamanca | - | Real Murcia | 2:0 n.V. | ||
| H: 25.11.1981 | R: 08.12.1981 | Sieger: UD Salamanca | ||||
| H | CA Osasuna | - | Real Sociedad | 1:1 | ||
| R | Real Sociedad | - | CA Osasuna | 3:1 | ||
| H: 25.11.1981 | R: 09.12.1981 | Sieger: Real Sociedad | ||||
| H | Sevilla Atlético | - | Hércules CF | 0:2 | ||
| R | Hércules CF | - | Sevilla Atlético | 3:3 | ||
| H: 25.11.1981 | R: 08.12.1981 | Sieger: Hércules CF | ||||
| H | Sporting Gijón | - | CD Castellón | 3:1 | ||
| R | CD Castellón | - | Sporting Gijón | 2:1 | ||
| H: 25.11.1981 | R: 09.12.1981 | Sieger: Sporting Gijón | ||||
| H | Espanyol Barcelona | - | Real Zaragoza | 2:0 | ||
| R | Real Zaragoza | - | Espanyol Barcelona | 1:2 | ||
| H: 09.12.1981 | R: 23.12.1981 | Sieger: Espanyol Barcelona | ||||
