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| 29.09.2021 | 17:00 | Rayo Vallecano | - | Sporting de Huelva | 0:0 (0:0) | |
| 17:30 | Sevilla FC | - | Madrid CFF | 2:2 (1:0) | ||
| 18:00 | Villarreal CF | - | FC Barcelona | 0:8 (0:3) | ||
| 18:00 | Levante UD | - | SD Eibar | 5:0 (0:0) | ||
| 19:00 | Valencia CF | - | Athletic Bilbao | 1:3 (1:1) | ||
| 19:00 | Real Madrid | - | Real Sociedad | 0:1 (0:1) | ||
| 20:00 | Atlético Madrid | - | CD Alavés | 3:2 (2:1) | ||
| 20:00 | Real Betis | - | UDG Tenerife Sur | 2:2 (0:1) |
| # | Mannschaft | Sp. | S. | U. | N. | Tore | Dif. | Pk. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
FC Barcelona | 4 | 4 | 0 | 0 | 26:0 | 26 | 12 |
| 2 |
|
Atlético Madrid | 4 | 4 | 0 | 0 | 13:2 | 11 | 12 |
| 3 |
|
Real Sociedad | 4 | 4 | 0 | 0 | 8:1 | 7 | 12 |
| 4 |
|
Athletic Bilbao | 4 | 3 | 0 | 1 | 7:3 | 4 | 9 |
| 5 |
|
CD Alavés | 4 | 3 | 0 | 1 | 8:5 | 3 | 9 |
| 6 |
|
Levante UD | 4 | 2 | 2 | 0 | 10:1 | 9 | 8 |
| 7 |
|
Madrid CFF | 4 | 2 | 1 | 1 | 8:7 | 1 | 7 |
| 8 |
|
Villarreal CF | 4 | 1 | 1 | 2 | 1:10 | -9 | 4 |
| 9 |
|
Sporting de Huelva | 4 | 0 | 3 | 1 | 2:5 | -3 | 3 |
| 10 |
|
SD Eibar | 4 | 1 | 0 | 3 | 4:10 | -6 | 3 |
| 11 |
|
Sevilla FC | 4 | 0 | 2 | 2 | 4:7 | -3 | 2 |
| 12 |
|
Real Betis | 4 | 0 | 2 | 2 | 4:10 | -6 | 2 |
|
UDG Tenerife Sur | 4 | 0 | 2 | 2 | 4:10 | -6 | 2 | |
| 14 |
|
Real Madrid | 4 | 0 | 1 | 3 | 1:8 | -7 | 1 |
| 15 |
|
Rayo Vallecano | 4 | 0 | 1 | 3 | 3:11 | -8 | 1 |
| 16 |
|
Valencia CF | 4 | 0 | 1 | 3 | 4:17 | -13 | 1 |
| Champions League | |
| Champions League Quali. | |
| Abstieg |
