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| 31.10.2021 | 11:00 | Real Betis | - | Athletic Bilbao | 4:2 (4:0) | |
| 11:00 | Levante UD | - | Sporting de Huelva | 0:0 (0:0) | ||
| 12:00 | Atlético Madrid | - | Villarreal CF | 3:0 (2:0) | ||
| 12:00 | CD Alavés | - | UDG Tenerife Sur | 1:1 (1:1) | ||
| 12:00 | FC Barcelona | - | Real Sociedad | 8:1 (3:1) | ||
| 12:00 | Rayo Vallecano | - | Sevilla FC | 1:0 (0:0) | ||
| 17:00 | Real Madrid | - | Valencia CF | 2:1 (2:0) | ||
| 18:00 | Madrid CFF | - | SD Eibar | 1:3 (0:1) |
| # | Mannschaft | Sp. | S. | U. | N. | Tore | Dif. | Pk. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
FC Barcelona | 8 | 8 | 0 | 0 | 51:2 | 49 | 24 |
| 2 |
|
Real Sociedad | 8 | 6 | 0 | 2 | 16:11 | 5 | 18 |
| 3 |
|
Atlético Madrid | 8 | 5 | 2 | 1 | 19:8 | 11 | 17 |
| 4 |
|
Athletic Bilbao | 8 | 5 | 1 | 2 | 13:8 | 5 | 16 |
| 5 |
|
Levante UD | 8 | 4 | 3 | 1 | 12:3 | 9 | 15 |
| 6 |
|
CD Alavés | 8 | 4 | 2 | 2 | 11:15 | -4 | 14 |
| 7 |
|
Real Betis | 8 | 3 | 2 | 3 | 15:18 | -3 | 11 |
| 8 |
|
Madrid CFF | 8 | 3 | 2 | 3 | 16:17 | -1 | 11 |
| 9 |
|
UDG Tenerife Sur | 8 | 2 | 4 | 2 | 10:12 | -2 | 10 |
| 10 |
|
Sevilla FC | 8 | 2 | 3 | 3 | 9:9 | 0 | 9 |
| 11 |
|
SD Eibar | 8 | 3 | 0 | 5 | 13:15 | -2 | 9 |
| 12 |
|
Real Madrid | 8 | 2 | 1 | 5 | 5:15 | -10 | 7 |
| 13 |
|
Sporting de Huelva | 8 | 0 | 5 | 3 | 2:11 | -9 | 5 |
| 14 |
|
Rayo Vallecano | 8 | 1 | 1 | 6 | 5:19 | -14 | 4 |
| 15 |
|
Villarreal CF | 8 | 1 | 1 | 6 | 2:21 | -19 | 4 |
| 16 |
|
Valencia CF | 8 | 1 | 1 | 6 | 7:22 | -15 | 4 |
| Champions League | |
| Champions League Quali. | |
| Abstieg |
