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| H | 1. FC Union Berlin | - | Union Saint-Gilloise | 3:3 (1:1) | ||
| R | Union Saint-Gilloise | - | 1. FC Union Berlin | 3:0 (1:0) | ||
| H: 09.03.2023 18:45 | R: 16.03.2023 21:00 | Sieger: Union Saint-Gilloise | ||||
| H | Bayer Leverkusen | - | Ferencvárosi TC | 2:0 (1:0) | ||
| R | Ferencvárosi TC | - | Bayer Leverkusen | 0:2 (0:1) | ||
| H: 09.03.2023 18:45 | R: 16.03.2023 21:00 | Sieger: Bayer Leverkusen | ||||
| H | Sporting CP | - | Arsenal FC | 2:2 (1:1) | ||
| R | Arsenal FC | - | Sporting CP | 3:5 (1:0, 1:1, 1:1) i.E. | ||
| H: 09.03.2023 18:45 | R: 16.03.2023 21:00 | Sieger: Sporting CP | ||||
| H | AS Roma | - | Real Sociedad | 2:0 (1:0) | ||
| R | Real Sociedad | - | AS Roma | 0:0 (0:0) | ||
| H: 09.03.2023 18:45 | R: 16.03.2023 21:00 | Sieger: AS Roma | ||||
| H | Sevilla FC | - | Fenerbahçe | 2:0 (0:0) | ||
| R | Fenerbahçe | - | Sevilla FC | 1:0 (1:0) | ||
| H: 09.03.2023 21:00 | R: 16.03.2023 18:45 | Sieger: Sevilla FC | ||||
| H | Juventus | - | SC Freiburg | 1:0 (0:0) | ||
| R | SC Freiburg | - | Juventus | 0:2 (0:1) | ||
| H: 09.03.2023 21:00 | R: 16.03.2023 18:45 | Sieger: Juventus | ||||
| H | Manchester United | - | Real Betis | 4:1 (1:1) | ||
| R | Real Betis | - | Manchester United | 0:1 (0:0) | ||
| H: 09.03.2023 21:00 | R: 16.03.2023 18:45 | Sieger: Manchester United | ||||
| H | Shakhtar Donetsk | - | Feyenoord | 1:1 (0:0) | ||
| R | Feyenoord | - | Shakhtar Donetsk | 7:1 (3:0) | ||
| H: 09.03.2023 21:00 | R: 16.03.2023 18:45 | Sieger: Feyenoord | ||||
