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| H | Atlético Junior | - | Boca Juniors | 3:3 (3:1) | ||
| R | Boca Juniors | - | Atlético Junior | 4:0 (2:0) | ||
| H: 18.05.2005 01:15 | R: 27.05.2005 00:05 | Sieger: Boca Juniors | ||||
| H | LDU Quito | - | River Plate | 2:1 (1:1) | ||
| R | River Plate | - | LDU Quito | 4:2 (2:0) | ||
| H: 18.05.2005 03:30 | R: 27.05.2005 02:15 | Sieger: River Plate | ||||
| H | Banfield | - | Independiente Medellín | 3:0 (0:0) | ||
| R | Independiente Medellín | - | Banfield | 0:2 (0:0) | ||
| H: 19.05.2005 00:20 | R: 25.05.2005 02:00 | Sieger: Banfield | ||||
| H | Palmeiras | - | São Paulo FC | 0:1 (0:0) | ||
| R | São Paulo FC | - | Palmeiras | 2:0 (0:0) | ||
| H: 19.05.2005 02:40 | R: 26.05.2005 01:15 | Sieger: São Paulo FC | ||||
| H | CF Pachuca | - | Deportivo Guadalajara | 1:1 (1:0) | ||
| R | Deportivo Guadalajara | - | CF Pachuca | 3:1 (1:1) | ||
| H: 19.05.2005 04:50 | R: 25.05.2005 04:30 | Sieger: Deportivo Guadalajara | ||||
| H | Athletico Paranaense | - | Cerro Porteño | 2:1 (1:0) | ||
| R | Cerro Porteño | - | Athletico Paranaense | 4:5 (2:1, 2:1, 2:1) i.E. | ||
| H: 20.05.2005 00:15 | R: 26.05.2005 23:15 | Sieger: Athletico Paranaense | ||||
| H | Universidad de Chile | - | Santos FC | 2:1 (0:0) | ||
| R | Santos FC | - | Universidad de Chile | 3:0 (1:0) | ||
| H: 20.05.2005 02:30 | R: 26.05.2005 00:45 | Sieger: Santos FC | ||||
| H | Once Caldas | - | UANL Tigres | 1:1 (0:1) | ||
| R | UANL Tigres | - | Once Caldas | 2:1 (0:1) | ||
| H: 20.05.2005 04:45 | R: 27.05.2005 04:45 | Sieger: UANL Tigres | ||||
