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| H | Corinthians SP | - | Estudiantes | 1:0 (1:0) | ||
| R | Estudiantes | - | Corinthians SP | 2:3 (1:0, 1:0) i.E. | ||
| H: 23.08.2023 02:30 | R: 30.08.2023 02:30 | Sieger: Corinthians SP | ||||
| H | Botafogo - RJ | - | Defensa y Justicia | 1:1 (0:0) | ||
| R | Defensa y Justicia | - | Botafogo - RJ | 2:1 (1:1) | ||
| H: 24.08.2023 00:00 | R: 31.08.2023 00:00 | Sieger: Defensa y Justicia | ||||
| H | América - MG | - | Fortaleza | 1:3 (0:3) | ||
| R | Fortaleza | - | América - MG | 2:1 (1:0) | ||
| H: 25.08.2023 00:00 | R: 01.09.2023 00:00 | Sieger: Fortaleza | ||||
| H | LDU Quito | - | São Paulo FC | 2:1 (2:0) | ||
| R | São Paulo FC | - | LDU Quito | 4:5 (0:0, 1:0) i.E. | ||
| H: 25.08.2023 00:00 | R: 01.09.2023 00:00 | Sieger: LDU Quito | ||||
