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| H | Libertad | - | Fortaleza | 0:1 (0:1) | ||
| R | Fortaleza | - | Libertad | 1:1 (0:1) | ||
| H: 02.08.2023 00:00 | R: 09.08.2023 00:00 | Sieger: Fortaleza | ||||
| H | Emelec | - | Defensa y Justicia | 1:2 (1:0) | ||
| R | Defensa y Justicia | - | Emelec | 1:0 (0:0) | ||
| H: 02.08.2023 02:00 | R: 09.08.2023 02:00 | Sieger: Defensa y Justicia | ||||
| H | Corinthians SP | - | Newell's Old Boys | 2:1 (0:1) | ||
| R | Newell's Old Boys | - | Corinthians SP | 0:0 (0:0) | ||
| H: 02.08.2023 02:30 | R: 09.08.2023 02:30 | Sieger: Corinthians SP | ||||
| H | Botafogo - RJ | - | Guaraní | 2:1 (0:1) | ||
| R | Guaraní | - | Botafogo - RJ | 0:0 (0:0) | ||
| H: 03.08.2023 00:00 | R: 10.08.2023 00:00 | Sieger: Botafogo - RJ | ||||
| H | Estudiantes | - | Goiás - GO | 3:0 (0:0) | ||
| R | Goiás - GO | - | Estudiantes | 0:2 (0:1) | ||
| H: 03.08.2023 00:00 | R: 10.08.2023 00:00 | Sieger: Estudiantes | ||||
| H | San Lorenzo | - | São Paulo FC | 1:0 (0:0) | ||
| R | São Paulo FC | - | San Lorenzo | 2:0 (1:0) | ||
| H: 04.08.2023 00:00 | R: 11.08.2023 00:00 | Sieger: São Paulo FC | ||||
| H | Ñublense | - | LDU Quito | 0:1 (0:0) | ||
| R | LDU Quito | - | Ñublense | 4:3 (1:1, 2:3) i.E. | ||
| H: 04.08.2023 02:00 | R: 11.08.2023 02:00 | Sieger: LDU Quito | ||||
| H | América - MG | - | Red Bull Bragantino | 1:1 (0:1) | ||
| R | Red Bull Bragantino | - | América - MG | 3:4 (2:2, 3:3) i.E. | ||
| H: 04.08.2023 02:00 | R: 11.08.2023 02:00 | Sieger: América - MG | ||||
