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| H | Colo-Colo | - | América - MG | 2:1 (0:0) | ||
| R | América - MG | - | Colo-Colo | 5:1 (3:0) | ||
| H: 12.07.2023 00:00 | R: 19.07.2023 00:00 | Sieger: América - MG | ||||
| H | Barcelona | - | Estudiantes | 2:1 (1:1) | ||
| R | Estudiantes | - | Barcelona | 4:0 (3:0) | ||
| H: 12.07.2023 02:00 | R: 19.07.2023 02:00 | Sieger: Estudiantes | ||||
| H | Corinthians SP | - | Universitario de Deportes | 1:0 (0:0) | ||
| R | Universitario de Deportes | - | Corinthians SP | 1:2 (0:0) | ||
| H: 12.07.2023 02:30 | R: 19.07.2023 02:30 | Sieger: Corinthians SP | ||||
| H | Patronato de Paraná | - | Botafogo - RJ | 0:2 (0:0) | ||
| R | Botafogo - RJ | - | Patronato de Paraná | 1:1 (1:0) | ||
| H: 13.07.2023 00:00 | R: 20.07.2023 00:00 | Sieger: Botafogo - RJ | ||||
| H | Sporting Cristal | - | Emelec | 0:1 (0:0) | ||
| R | Emelec | - | Sporting Cristal | 0:0 (0:0) | ||
| H: 13.07.2023 02:00 | R: 20.07.2023 02:00 | Sieger: Emelec | ||||
| H | Independiente Medellín | - | San Lorenzo | 0:1 (0:0) | ||
| R | San Lorenzo | - | Independiente Medellín | 2:0 (1:0) | ||
| H: 13.07.2023 02:00 | R: 20.07.2023 02:00 | Sieger: San Lorenzo | ||||
| H | Ñublense | - | Audax Italiano | 0:0 (0:0) | ||
| R | Audax Italiano | - | Ñublense | 0:1 (0:0) | ||
| H: 14.07.2023 00:00 | R: 22.07.2023 00:00 | Sieger: Ñublense | ||||
| H | Libertad | - | Tigre | 2:1 (0:1) | ||
| R | Tigre | - | Libertad | 0:1 (0:1) | ||
| H: 14.07.2023 02:00 | R: 21.07.2023 02:00 | Sieger: Libertad | ||||
