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| 02.02.2022 | 12:00 | Real Betis | - | CD Alavés | 4:1 (1:0) | |
| 12:00 | UDG Tenerife Sur | - | Sporting de Huelva | 1:0 (0:0) | ||
| 16:30 | Atlético Madrid | - | Madrid CFF | 3:2 (2:1) | ||
| 17:00 | Sevilla FC | - | Villarreal CF | 0:3 (0:0) | ||
| 17:00 | Rayo Vallecano | - | Valencia CF | 1:1 (0:1) | ||
| 17:00 | Levante UD | - | FC Barcelona | 1:4 (0:3) | ||
| 18:00 | Real Sociedad | - | Real Madrid | 1:3 (0:1) | ||
| 19:00 | Athletic Bilbao | - | SD Eibar | 3:1 (3:1) |
| # | Mannschaft | Sp. | S. | U. | N. | Tore | Dif. | Pk. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
FC Barcelona | 20 | 20 | 0 | 0 | 115:6 | 109 | 60 |
| 2 |
|
Real Sociedad | 20 | 15 | 1 | 4 | 45:29 | 16 | 46 |
| 3 |
|
Atlético Madrid | 20 | 11 | 5 | 4 | 44:21 | 23 | 38 |
| 4 |
|
Real Madrid | 20 | 12 | 2 | 6 | 31:23 | 8 | 38 |
| 5 |
|
UDG Tenerife Sur | 20 | 11 | 4 | 5 | 28:29 | -1 | 37 |
| 6 |
|
Athletic Bilbao | 20 | 11 | 3 | 6 | 34:27 | 7 | 36 |
| 7 |
|
Levante UD | 20 | 8 | 5 | 7 | 32:26 | 6 | 29 |
| 8 |
|
Sevilla FC | 20 | 7 | 6 | 7 | 23:32 | -9 | 27 |
| 9 |
|
CD Alavés | 20 | 7 | 5 | 8 | 23:37 | -14 | 26 |
| 10 |
|
Real Betis | 20 | 7 | 4 | 9 | 27:40 | -13 | 25 |
| 11 |
|
Villarreal CF | 20 | 6 | 2 | 12 | 20:46 | -26 | 20 |
| 12 |
|
Madrid CFF | 20 | 6 | 2 | 12 | 33:48 | -15 | 20 |
| 13 |
|
SD Eibar | 20 | 5 | 1 | 14 | 21:38 | -17 | 16 |
| 14 |
|
Valencia CF | 20 | 4 | 3 | 13 | 19:42 | -23 | 15 |
| 15 |
|
Sporting de Huelva | 20 | 1 | 10 | 9 | 13:34 | -21 | 13 |
| 16 |
|
Rayo Vallecano | 20 | 1 | 3 | 16 | 14:44 | -30 | 6 |
| Champions League | |
| Champions League Quali. | |
| Abstieg |
