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| 06.02.2022 | 11:30 | Real Sociedad | - | Atlético Madrid | 2:2 (1:1) | |
| 12:00 | CD Alavés | - | Sevilla FC | 1:1 (1:1) | ||
| 12:00 | FC Barcelona | - | SD Eibar | 7:0 (5:0) | ||
| 12:00 | Villarreal CF | - | Rayo Vallecano | 1:0 (0:0) | ||
| 12:00 | Sporting de Huelva | - | Athletic Bilbao | 2:0 (1:0) | ||
| 12:00 | Madrid CFF | - | UDG Tenerife Sur | 0:1 (0:0) | ||
| 12:00 | Real Madrid | - | Real Betis | 1:0 (0:0) | ||
| 17:30 | Valencia CF | - | Levante UD | 2:0 (1:0) |
| # | Mannschaft | Sp. | S. | U. | N. | Tore | Dif. | Pk. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
FC Barcelona | 21 | 21 | 0 | 0 | 122:6 | 116 | 63 |
| 2 |
|
Real Sociedad | 21 | 15 | 2 | 4 | 47:31 | 16 | 47 |
| 3 |
|
Real Madrid | 21 | 13 | 2 | 6 | 32:23 | 9 | 41 |
| 4 |
|
UDG Tenerife Sur | 21 | 12 | 4 | 5 | 29:29 | 0 | 40 |
| 5 |
|
Atlético Madrid | 21 | 11 | 6 | 4 | 46:23 | 23 | 39 |
| 6 |
|
Athletic Bilbao | 21 | 11 | 3 | 7 | 34:29 | 5 | 36 |
| 7 |
|
Levante UD | 21 | 8 | 5 | 8 | 32:28 | 4 | 29 |
| 8 |
|
Sevilla FC | 21 | 7 | 7 | 7 | 24:33 | -9 | 28 |
| 9 |
|
CD Alavés | 21 | 7 | 6 | 8 | 24:38 | -14 | 27 |
| 10 |
|
Real Betis | 21 | 7 | 4 | 10 | 27:41 | -14 | 25 |
| 11 |
|
Villarreal CF | 21 | 7 | 2 | 12 | 21:46 | -25 | 23 |
| 12 |
|
Madrid CFF | 21 | 6 | 2 | 13 | 33:49 | -16 | 20 |
| 13 |
|
Valencia CF | 21 | 5 | 3 | 13 | 21:42 | -21 | 18 |
| 14 |
|
Sporting de Huelva | 21 | 2 | 10 | 9 | 15:34 | -19 | 16 |
| 15 |
|
SD Eibar | 21 | 5 | 1 | 15 | 21:45 | -24 | 16 |
| 16 |
|
Rayo Vallecano | 21 | 1 | 3 | 17 | 14:45 | -31 | 6 |
| Champions League | |
| Champions League Quali. | |
| Abstieg |
