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| 24.07.2010 | 16:00 | Raith Rovers | - | Cowdenbeath FC | 0:1 (0:0) | |
| 16:00 | Airdrie United FC | - | Ayr United | 1:2 (0:0) | ||
| 16:00 | Dunfermline Athletic | - | Arbroath FC | 1:0 (0:0) | ||
| 16:00 | Stranraer FC | - | East Stirlingshire FC | 1:2 (0:0, 1:1) n.V. | ||
| 16:00 | Stenhousemuir FC | - | Annan Athletic | 3:2 (3:0) | ||
| 16:00 | East Fife FC | - | Brechin City FC | 4:3 (0:1, 2:2) n.V. | ||
| 16:00 | Queen Of The South | - | Albion Rovers | 2:1 (1:0) | ||
| 16:00 | Elgin City | - | Ross County FC | 1:2 (0:0) | ||
| 16:00 | Queen's Park FC | - | Livingston FC | 3:2 (1:1, 1:1) n.V. | ||
| 16:00 | Partick Thistle | - | Clyde FC | 2:1 (1:1) | ||
| 16:00 | Peterhead FC | - | Montrose FC | 5:0 (1:0) | ||
| 16:00 | Stirling Albion FC | - | Falkirk FC | 3:1 (0:0, 0:0, 0:0) i.E. | ||
| 16:00 | Dundee FC | - | Alloa Athletic | 2:1 (0:0) | ||
| 25.07.2010 | 16:00 | Dumbarton FC | - | Greenock Morton FC | 3:4 (0:0, 0:0, 0:0) i.E. |
