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| 31.07.2010 | 16:00 | Albion Rovers | - | Airdrie United FC | 0:1 (0:0) | |
| 16:00 | Annan Athletic | - | Partick Thistle | 0:1 (0:0) | ||
| 16:00 | Clyde FC | - | Cowdenbeath FC | 2:1 (0:0) | ||
| 16:00 | Dundee FC | - | Montrose FC | 3:0 (1:0) | ||
| 16:00 | Dunfermline Athletic | - | Arbroath FC | 5:2 (1:1) | ||
| 16:00 | Elgin City | - | Ayr United | 3:2 (1:1, 2:2) n.V. | ||
| 16:00 | Inverness CT | - | Queen's Park FC | 3:0 (1:0) | ||
| 16:00 | Peterhead FC | - | Berwick Rangers | 1:0 (0:0) | ||
| 16:00 | Queen Of The South | - | Dumbarton FC | 5:1 (2:0) | ||
| 16:00 | Raith Rovers | - | East Fife FC | 4:1 (3:0) | ||
| 16:00 | Ross County FC | - | Livingston FC | 2:1 (1:0) | ||
| 16:00 | Stenhousemuir FC | - | Brechin City FC | 1:3 (1:2) | ||
| 16:00 | Stirling Albion FC | - | Forfar Athletic | 1:2 (0:1) | ||
| 16:00 | Stranraer FC | - | Greenock Morton FC | 1:7 (0:2) | ||
| 01.08.2010 | 16:00 | East Stirlingshire FC | - | Alloa Athletic | 1:2 (1:1) |
