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| 14.08.2012 | 20:30 | Annan Athletic | - | Stenhousemuir FC | 0:3 (0:2) | |
| 20:30 | Queen's Park FC | - | Partick Thistle | 4:5 (1:2) | ||
| 20:30 | Greenock Morton FC | - | Queen Of The South | 1:2 (1:0, 1:1) n.V. | ||
| 20:45 | Cowdenbeath FC | - | East Fife FC | 3:0 (1:0) | ||
| 20:45 | Raith Rovers | - | Montrose FC | 5:2 (3:1) | ||
| 20:45 | Arbroath FC | - | Forfar Athletic | 3:2 (3:2) | ||
| 20:45 | East Stirlingshire FC | - | Airdrie United FC | 3:0 (2:0) | ||
| 21.08.2012 | 20:45 | Falkirk FC | - | Rangers FC | 0:1 (0:1) |
