 |
 |
| Primera | 03.01.2022 | Villarreal CF | - | Levante UD | 5:0 | 13.462 |
| Primera | 09.01.2022 | Villarreal CF | - | Atlético Madrid | 2:2 | 14.127 |
| Primera | 22.01.2022 | Villarreal CF | - | RCD Mallorca | 3:0 | 13.207 |
| Primera | 12.02.2022 | Villarreal CF | - | Real Madrid | 0:0 | 17.894 |
| Ch. League | 22.02.2022 | Villarreal CF | - | Juventus | 1:1 | 17.686 |
| Primera | 27.02.2022 | Villarreal CF | - | Espanyol Barcelona | 5:1 | 15.600 |
| Primera | 12.03.2022 | Villarreal CF | - | RC Celta | 1:0 | 14.929 |
| Ch. League | 06.04.2022 | Villarreal CF | - | Bayern München | 1:0 | 21.626 |
| Primera | 09.04.2022 | Villarreal CF | - | Athletic Club | 1:1 | 16.603 |
| Primera | 19.04.2022 | Villarreal CF | - | Valencia CF | 2:0 | 13.570 |
| Ch. League | 03.05.2022 | Villarreal CF | - | Liverpool FC | 2:3 | 23.665 |
| Primera | 08.05.2022 | Villarreal CF | - | Sevilla FC | 1:1 | 17.461 |
| Primera | 15.05.2022 | Villarreal CF | - | Real Sociedad | 1:2 | 16.689 |
| Primera | 04.09.2022 | Villarreal CF | - | Elche CF | 4:0 | 13.915 |
| Primera | 31.12.2022 | Villarreal CF | - | Valencia CF | 2:1 | 19.247 |
Spanien