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| 20.09.2011 | 20:45 | St. Johnstone FC | - | St. Mirren FC | 0:2 (0:2) | |
| 20:45 | Kilmarnock FC | - | Queen Of The South | 5:0 (2:0) | ||
| 20:45 | Motherwell FC | - | Hibernian FC | 6:7 (2:1, 2:2, 2:2) i.E. | ||
| 20:45 | Aberdeen FC | - | East Fife FC | 3:4 (1:1, 3:3, 3:3) i.E. | ||
| 20:45 | Airdrie United FC | - | Dundee United | 0:2 (0:1) | ||
| 21.09.2011 | 20:15 | Ross County FC | - | Celtic FC | 0:2 (0:1) | |
| 20:45 | Falkirk FC | - | Rangers FC | 3:2 (0:0) | ||
| 20:45 | Ayr United | - | Heart of Midlothian | 4:1 (0:0, 1:1, 1:1) i.E. |
